Surface Treatment
by: Eric Finson and Stephen L. Kaplan
Packaging Technology
Introduction
In almost every industry, the nature of a material's surface can
drastically affect a product's success. The reasons can be quite different, varying from
purely aesthetic to functional. This is particularly true for packaging applications. To
the consumer at the point of purchase a package must appear attractive and clean as well
as preserve its contents. Obtaining the appropriate balance of structural, aesthetic, and
functional (barrier) properties often requires compounding specific additives into the
bulk material or combining several separate materials into a composite structure. The type
of specialty additives often used as bulk treatments may include but are not limited to
antistats, antiblocks, slip modifiers, plasticizers, fillers, and stabilizers for UV,
oxygen, and heat. The operations or procedures used to take various raw materials and
fashion them into packaging structures is often referred to as "converting." A
surface treatment is frequently employed as part of the conversion process to alter the
surface characteristics of the specific material being used. Typical surface treatment
processes include altering the wettability of a substrate, improving the bondability of an
applied material or the elimination of accumulated static charge. Surface treatment
technologies can play a key role in the preparation of surfaces of the most commonly used
packaging substrates such as paper, plastic, foil, or metal/inorganic depositions for
subsequent processing steps. In many cases, packaging producers are required to select
specially formulated and expensive materials (eg, printing inks, adhesives, polymer films,
or structures) to ensure satisfactory performance. The alternative to this scenario is to
choose a material or combination of materials for their bulk properties and then modify
their surfaces to achieve appropriate performance attributes. Surface treatments can allow
the necessary modifications to packaging material surfaces without altering their bulk
properties so that individual or multilaminate composite packaging structures can meet or
exceed end use requirements.
Surface Preparations
Achieving adequate adhesion to polymers is a recurring and difficult
problem throughout the packaging industry. Historically, various surface treatments have
been used to improve the adhesion of coatings to plastics, including flame and corona,
mechanical abrasion, solvent cleaning or swelling followed by wet chemical etching, or the
application of specialized coatings in the form of chemical primers. Also, high energy
density treatments (1) such as ultraviolet (uv) radiation, electron-beam and
cold-gas-plasma methods have gained greater acceptance on a larger scale for substrate
surface modification. They provide a medium rich in reactive species, such as energetic
photons, electrons, free radicals, and ions, which, in turn, interact with the polymer
surface, changing its chemistry and/or morphology. These processes can be readily adopted
to modify surface properties of webs, films, and rigid containers, which are commonly
incorporated into packaging structures. The available surface treatment technologies are
summarized in Table 1.
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The Wiley Encyclopedia of Packaging Technology, Second Edition, Edited by Aaron L.
Brody and Kenneth S. Marsh - ISBN 0-471-063975-5 © 1997 by John Wiley & Sons, Inc. |